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Oil Analysis Reference Guide

Comprehensive limits and interpretation guide for lubricating oil and transformer oil analysis

Basic Oil Properties
Property Unit Normal Caution Critical Notes
Viscosity @ 40°C cSt ±5% of new oil ±10% of new oil >10% change Compare to baseline; ISO VG grade dependent
Total Acid Number (TAN) mg KOH/g < 0.2 0.2 - 0.5 > 0.5 Indicates oxidation; compare to new oil baseline
Moisture Content ppm < 100 100 - 250 > 250 Water contamination; hydraulics more sensitive
Oxidation Inhibitor (DBPC) % > 50% remaining 25-50% remaining < 25% remaining Antioxidant depletion tracking
RPVOT (Oxidation Stability) Minutes > 75% of new 50-75% of new < 50% of new Rotating Pressure Vessel Oxidation Test
Varnish Potential (MPC) ΔE < 15 15 - 30 > 30 Membrane Patch Colorimetry; varnish precursors
Wear Metal Elements Typical Industrial Limits (ppm)
Understanding Wear Metals

Wear metals indicate component degradation. Compare results to established baselines and trend over time. A sudden increase (>25% from previous sample) warrants investigation regardless of absolute value.

Element Symbol Normal Caution Critical Primary Sources
FeIron Wear < 30 30 - 75 > 75 Gears, bearings, shafts, cylinders
CrChromium Wear < 5 5 - 15 > 15 Rings, liners, exhaust valves, stainless steel
PbLead Wear < 10 10 - 30 > 30 Bearings (babbitt), solder
CuCopper Wear < 20 20 - 50 > 50 Bushings, thrust washers, oil coolers
SnTin Wear < 5 5 - 15 > 15 Bearings (babbitt overlay), bronze
AlAluminum Wear < 15 15 - 30 > 30 Pistons, bearings, housings, pumps
NiNickel Wear < 5 5 - 10 > 10 Valves, high-temp alloys, bearings
AgSilver Wear < 1 1 - 3 > 3 Silver-plated bearings, wrist pins
Contaminant Elements Typical Industrial Limits (ppm)
Element Symbol Normal Caution Critical Primary Sources
SiSilicon Contaminant < 10 10 - 25 > 25 Dirt ingression, seals, antifoam additive
BBoron Contaminant < 5 5 - 15 > 15 Coolant leak (antifreeze), some additives
NaSodium Contaminant < 10 10 - 25 > 25 Coolant leak, salt contamination, grease
MgMagnesium Contaminant < 5 5 - 15 > 15 Additives, seawater, some alloys
CaCalcium Contaminant < 10 10 - 30 > 30 Detergent additive, grease, hard water
KPotassium Contaminant < 5 5 - 15 > 15 Coolant leak, seawater
Additive Elements Monitor for Depletion
Additive Monitoring

Additive levels should be compared to new oil baseline. Significant depletion (>50%) indicates the oil may need replacement or top-up with fresh oil. Cross-contamination with different oil types will show unexpected additive patterns.

Element Symbol Function Action Level Notes
ZnZinc Additive Anti-wear (ZDDP) < 50% of new oil Often paired with phosphorus; EP additive
PPhosphorus Additive Anti-wear (ZDDP) < 50% of new oil Part of ZDDP package; EP additive
MoMolybdenum Additive Friction modifier Monitor trend Solid lubricant; may also indicate wear
BaBarium Additive Detergent/dispersant Monitor trend Rust inhibitor; less common today
ISO 4406 Particle Count Cleanliness
ISO 4406 Code Explanation

ISO 4406 cleanliness code consists of three numbers representing particle counts at >4μm, >6μm, and >14μm sizes per mL.

18 / 16 / 13

>4μm / >6μm / >14μm

ISO Code Reference
CodeParticles/mL (min)Particles/mL (max)
134080
1480160
15160320
16320640
176401,300
181,3002,500
192,5005,000
205,00010,000
2110,00020,000
Target Cleanliness by Application
Application Target ISO Code Filter Rating (β10) Notes
Servo Valves 14/12/9 3μm Most sensitive; tight clearances
Proportional Valves 15/13/10 5μm High precision hydraulics
Vane & Piston Pumps 16/14/11 10μm Industrial hydraulics
Gear Pumps 17/15/12 15μm Less sensitive
Steam Turbines 18/16/13 10μm Typical power generation
Industrial Gearboxes 18/16/14 25μm Circulating systems
Transformer Oil Physical/Chemical Tests IEEE C57.106
Property Unit Good Marginal Poor Test Method
Dielectric Strength kV > 30 25 - 30 < 25 ASTM D1816 / D877
Power Factor @ 25°C % < 0.5 0.5 - 2.0 > 2.0 ASTM D924
Interfacial Tension mN/m (dynes/cm) > 32 25 - 32 < 25 ASTM D971
Acid Number (Neutralization) mg KOH/g < 0.10 0.10 - 0.20 > 0.20 ASTM D974
Moisture Content ppm < 20 20 - 35 > 35 ASTM D1533
Color ASTM < 2.0 2.0 - 3.5 > 3.5 ASTM D1500
Oxidation Inhibitor % DBPC > 0.15 0.08 - 0.15 < 0.08 ASTM D2668/D4768
Specific Gravity @ 20°C - 0.86 - 0.90 - Outside range ASTM D1298
Dissolved Gas Analysis (DGA) IEEE C57.104
⚠️ Important Note

DGA interpretation requires considering gas ratios, rates of change (gassing rates), and transformer history. Single sample values should be compared against IEEE condition categories and historical trends.

Individual Gas Limits (ppm) - IEEE C57.104-2019
Gas Formula Condition 1
(Normal)
Condition 2
(Caution)
Condition 3
(Warning)
Primary Fault Indication
Hydrogen H₂ < 100 100 - 700 > 700 Partial discharge, arcing, corona
Methane CH₄ < 75 75 - 125 > 125 Low-temp thermal fault (150-300°C)
Ethane C₂H₆ < 65 65 - 100 > 100 Low-temp thermal fault (150-300°C)
Ethylene C₂H₄ < 50 50 - 100 > 100 High-temp thermal fault (>300°C)
Acetylene C₂H₂ < 1 1 - 9 > 9 Arcing, very high temp (>700°C)
Carbon Monoxide CO < 350 350 - 570 > 570 Cellulose (paper) degradation
Carbon Dioxide CO₂ < 2,500 2,500 - 4,000 > 4,000 Cellulose degradation, aging
Total Dissolved Combustible Gas (TDCG) - < 720 720 - 1,920 > 1,920 Sum of all combustible gases
Key Gas Ratios
Ratio Indicates
C₂H₂/C₂H₄ Arcing vs thermal fault
CH₄/H₂ Fault temperature
C₂H₄/C₂H₆ Thermal fault severity
CO₂/CO Paper aging rate (normal: 5-10)
Duval Triangle Fault Types
PD Partial Discharge
D1 Low Energy Discharge
D2 High Energy Discharge
T1 Thermal <300°C
T2 Thermal 300-700°C
T3 Thermal >700°C
DT Mix of Thermal & Electrical
Furan Analysis - Paper Insulation Condition IEEE C57.104
Paper Degradation Indicator

Furans are byproducts of cellulose (paper insulation) degradation. 2-FAL (2-Furfuraldehyde) is the most significant indicator. Furan levels correlate with remaining paper life and Degree of Polymerization (DP).

Furan Compound Abbreviation Normal (ppb) Caution (ppb) Critical (ppb)
2-Furfuraldehyde 2-FAL < 100 100 - 1,000 > 1,000
5-Hydroxymethyl-2-furfural 5-HMF < 100 100 - 500 > 500
Furfuryl Alcohol 2-FOL < 100 100 - 500 > 500
2-Acetylfuran 2-ACF < 100 100 - 500 > 500
5-Methyl-2-furfural 5-MEF < 100 100 - 500 > 500
Estimated Paper Condition from 2-FAL
2-FAL (ppb) Estimated DP Paper Condition Estimated Life
< 100 > 700 Good > 20 years
100 - 1,000 450 - 700 Moderate Aging 10-20 years
1,000 - 2,500 250 - 450 Significant Aging 5-10 years
> 2,500 < 250 Severe Degradation End of life approaching
Reference Documents

Download comprehensive IEEE transformer oil analysis guidelines

Download IEEE C57.104 Reference Guide (PDF)

* Place your IEEE document in the downloads folder and update the link

Oil Sampling Best Practices
Before Sampling
  • Equipment should be at normal operating temperature
  • Run equipment for minimum 30 minutes before sampling
  • Use clean, dedicated sampling equipment
  • Flush sample point with 5-10 volumes before collecting
  • Label containers with equipment ID, date, time, and oil hours
  • Use appropriate sample containers for each test type
Sample Container Requirements
Test Type Container
Elemental Analysis / Wear Metals Clean plastic or glass bottle
Particle Count Pre-cleaned bottle (low particle)
Moisture / Karl Fischer Glass syringe or sealed bottle
DGA (Transformers) Glass syringe, no air bubbles
Dielectric Strength Clean 1L glass container
Sampling Frequency Guidelines
Equipment Type Criticality: High Criticality: Medium Criticality: Low
Steam/Gas Turbines Monthly Quarterly Semi-annually
Hydraulic Systems Monthly Quarterly Semi-annually
Gearboxes Quarterly Semi-annually Annually
Compressors Monthly Quarterly Semi-annually
Power Transformers (>10MVA) Quarterly Semi-annually Annually
Distribution Transformers Annually Annually Every 2-3 years
⚠️ Common Sampling Errors to Avoid
  • Sampling from drain ports (collects settled debris)
  • Sampling cold equipment (oil not representative)
  • Using dirty or reused containers
  • Not flushing sample point adequately
  • Introducing air bubbles (especially for DGA samples)
  • Mislabeling or incomplete sample information
  • Delaying shipping (especially moisture-sensitive tests)